WebSep 23, 2024 · Very recently, we presented a new version of pillararene-derived macrocyclic arenes named leggero pillar [n]arenes [ 42, 43 ], in which two substituents on a single one of the units of traditional pillararenes were selectively removed to expand their structural flexibility and cavity adaptability. WebPagoda-Skyline, Inc. is a non-profit, citizen volunteer organization dedicated to the restoration and preservation of the Pagoda, the Fire Tower and the Skyline Drive area. …
Bottom-Up Solid-State Molecular Assembly via Guest-Induced ...
WebDOI: 10.6023/CJOC202400035 Corpus ID: 236648117; Pagoda[5]arene: An Emerging Anthracene-Based Macrocyclic Arene with a Deep and Well-Defined Cavity … WebApr 15, 2024 · A new type of macrocyclic arenes, named as pagoda[4]arene (P4) and i-pagoda[4]arene (i-P4), were conveniently synthesized by TFA-catalyzed one-pot condensation of 2,6-dimethoxylanthracene and paraformaldehyde in dichloromethane at room temperature. crick\\u0027s pizza princeton nc menu
Pagoda[5]arene with Large and Rigid Cavity for the Formation of …
WebNov 24, 2024 · The manipulation of molecular motions to construct highly ordered supramolecular architectures from chaos in the solid state is considered to be far more complex and challenging in comparison to that in solution. In this work, a bottom-up molecular assembly approach based on a newly designed skeleton-trimmed … WebJan 1, 2024 · A new type of macrocyclic arenes, named as pagoda[4]arene (P4) and i-pagoda[4]arene (i-P4), were conveniently synthesized by TFA-catalyzed one-pot … WebJan 10, 2024 · Herein, host-guest complexation between pagoda[n]arenes (n = 4, P4; n = 5, P5) and tropylium cation (G) was investigated in detail. It was found that both P4 and P5 showed surprisingly strong binding affinities toward the tropylium cation with association constants of more than 107 M-1 for the 1:1 host-guest complexes. The theoretical … malta imports